Online ISSN: 1521-3773 Print ISSN: 1433-7851
Angewandte Chemie International Edition
Volume
39, Issue
9,
2000.
© 2000 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany
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Online ISSN: 1521-3773 Print ISSN: 1433-7851 © 2000 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany |
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Cover Picture Joulia Larionova, Mathias Gross, Melanie Pilkington, Hanspeter Andres, Helen Stoeckli-Evans, Hans U. Güdel, Silvio Decurtins Published Online: 3 May 2000 DOI10.1002/(SICI)1521-3773(20000502)39:9<1519::AID-ANIE1519>3.0.CO;2-M |
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Dead Ends and Detours En Route to Total Syntheses of the 1990s Miguel A. Sierra, Maria C. de la Torre Published Online: 2 May 2000 DOI10.1002/(SICI)1521-3773(20000502)39:9<1538::AID-ANIE1538>3.0.CO;2-O |
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The Orbital Origins of Magnetism: From Atoms to Molecules to Ferromagnetic Alloys Gregory A. Landrum, Richard Dronskowski Published Online: 2 May 2000 DOI10.1002/(SICI)1521-3773(20000502)39:9<1560::AID-ANIE1560>3.0.CO;2-T |
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Atomic Glimpses on a Billion-Year-Old Molecular Machine Eric Westhof, Neocles Leontis Published Online: 2 May 2000 DOI10.1002/(SICI)1521-3773(20000502)39:9<1587::AID-ANIE1587>3.0.CO;2-K |
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How Does Tyrosinase Work? Recent Insights from Model Chemistry and Structural Biology
Heinz Decker, Renée Dillinger, Felix Tuczek Published Online: 2 May 2000 DOI10.1002/(SICI)1521-3773(20000502)39:9<1591::AID-ANIE1591>3.0.CO;2-H |
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From Molecular Flat Tapers, Discs, and Cones to Supramolecular Cylinders and Spheres using Fréchet-Type Monodendrons Modified on their Periphery Virgil Percec, Wook-Dong Cho, Goran Ungar, Duncan J. P. Yeardley Published Online: 2 May 2000 DOI10.1002/(SICI)1521-3773(20000502)39:9<1597::AID-ANIE1597>3.0.CO;2-I |
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Nickel-Catalyzed Cross-Coupling of Aryl Chlorides with Aryl Grignard Reagents
Volker P. W. Böhm, Thomas Weskamp, Christian W. K. Gstöttmayr, Wolfgang A. Herrmann Published Online: 2 May 2000 DOI10.1002/(SICI)1521-3773(20000502)39:9<1602::AID-ANIE1602>3.0.CO;2-N |
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High-Spin Molecules: A Novel Cyano-Bridged MnMo Molecular Cluster with a S=51/2 Ground State and Ferromagnetic Intercluster Ordering at Low Temperatures
Joulia Larionova, Mathias Gross, Melanie Pilkington, Hanspeter Andres, Helen Stoeckli-Evans, Hans U. Güdel, Silvio Decurtins Published Online: 2 May 2000 DOI10.1002/(SICI)1521-3773(20000502)39:9<1605::AID-ANIE1605>3.0.CO;2-5 |
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Reaction of Dichloromethyltris(trimethylsilyl)silane with Organolithium Reagents: Synthesis of an Intramolecularly Donor-Stabilized Silene Martin Mickoleit, Kathleen Schmohl, Rhett Kempe, Hartmut Oehme Published Online: 2 May 2000 DOI10.1002/(SICI)1521-3773(20000502)39:9<1610::AID-ANIE1610>3.0.CO;2-X |
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Linking Icosahedral, Strong Molecular Magnets {MoFe} to Layers - A Solid-State Reaction at Room Temperature
Achim Müller, Erich Krickemeyer, Samar K. Das, Paul Kögerler, Sabyasachi Sarkar, Hartmut Bögge, Marc Schmidtmann, Shatarupa Sarkar Published Online: 2 May 2000 DOI10.1002/(SICI)1521-3773(20000502)39:9<1612::AID-ANIE1612>3.0.CO;2-L |
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Thirty Electrons Trapped in a Spherical Matrix: A Molybdenum Oxide-Based Nanostructured Keplerate Reduced by 36 Electrons Achim Müller, Syed Qaiser Nazir Shah, Hartmut Bögge, Marc Schmidtmann, Paul Kögerler, Björn Hauptfleisch, Stefan Leiding, Kai Wittler Published Online: 2 May 2000 DOI10.1002/(SICI)1521-3773(20000502)39:9<1614::AID-ANIE1614>3.0.CO;2-9 |
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A Molecular Knot with Twelve Amide Groups - One-Step Synthesis, Crystal Structure, Chirality
Oliver Safarowsky, Martin Nieger, Roland Fröhlich, Fritz Vögtle Published Online: 2 May 2000 DOI10.1002/(SICI)1521-3773(20000502)39:9<1616::AID-ANIE1616>3.0.CO;2-Y |
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Highly Regioselective Oxygenation of C-H Bonds: Diamidomanganese Constructs with Attached Substrates as Catalyst Models Rayane F. Moreira, Paul M. Wehn, Dalibor Sames Published Online: 2 May 2000 DOI10.1002/(SICI)1521-3773(20000502)39:9<1618::AID-ANIE1618>3.0.CO;2-M |
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Solid-Phase Synthesis of Unprotected N-Glycopeptide Building Blocks for SPOT Synthesis of N-linked Glycopeptides Laurence Jobron, Gerd Hummel Published Online: 2 May 2000 DOI10.1002/(SICI)1521-3773(20000502)39:9<1621::AID-ANIE1621>3.0.CO;2-P |
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Can a Homometallic Chain Be Ferrimagnetic? Morsy A. M. Abu-Youssef, Albert Escuer, Mohamed A. S. Goher, Franz A. Mautner, Guido J. Rei? Ramon Vicente Published Online: 2 May 2000 DOI10.1002/(SICI)1521-3773(20000502)39:9<1624::AID-ANIE1624>3.0.CO;2-7 |
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Stereoselectivity in the Formation of a Cyclic Trinuclear cis-Dioxomolybdenum(VI) Complex of a Chiral Siderophore Analogue
Anne-Kathrin Duhme-Klair, Guido Vollmer, Craig Mars, Roland Fröhlich Published Online: 2 May 2000 DOI10.1002/(SICI)1521-3773(20000502)39:9<1626::AID-ANIE1626>3.0.CO;2-W |
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An Enzyme-Labile Safety Catch Linker for Combinatorial Synthesis on a Soluble Polymeric Support Uwe Grether, Herbert Waldmann Published Online: 2 May 2000 DOI10.1002/(SICI)1521-3773(20000502)39:9<1629::AID-ANIE1629>3.0.CO;2-E |
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The First Structurally Characterized Metal Complex with the Molecular Unit M=C=C=C=CR2 Kerstin Ilg, Helmut Werner Published Online: 2 May 2000 DOI10.1002/(SICI)1521-3773(20000502)39:9<1632::AID-ANIE1632>3.0.CO;2-H |
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Homoleptic Carbonyl Ni-Pd Clusters: Synthesis of [Ni16Pd16(CO)40]4- and [Ni26Pd20(CO)54]6- and Structural Characterization of [NnBu4]4[Ni16Pd16(CO)40] Cristina Femoni, M. Carmela Iapalucci, Giuliano Longoni, Per H. Svensson, Joanna Wolowska Published Online: 2 May 2000 DOI10.1002/(SICI)1521-3773(20000502)39:9<1635::AID-ANIE1635>3.0.CO;2-# |
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[Li(thf)4]2+[Ga12(C13H9)10]2-: The First Molecular Compound with an Icosahedral Ga12 Framework
Andreas Schnepf, Gregor Stößer, Ralf Köppe, Hansgeorg Schnöckel Published Online: 2 May 2000 DOI10.1002/(SICI)1521-3773(20000502)39:9<1637::AID-ANIE1637>3.0.CO;2-O |
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Novel Oxyfunctionalized Phosphonite Ligands for the Hydroformylation of Isomeric n-Olefins Detlef Selent, Klaus-Diether Wiese, Dirk Röttger, Armin Börner Published Online: 2 May 2000 DOI10.1002/(SICI)1521-3773(20000502)39:9<1639::AID-ANIE1639>3.0.CO;2-C |
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First Noncovalently Bound Calix[4]arene-GdIII-Albumin Complex L. Henry Bryant, Jr., Alexander T. Yordanov, Jenny J. Linnoila, Martin W. Brechbiel, Joseph A. Frank Published Online: 2 May 2000 DOI10.1002/(SICI)1521-3773(20000502)39:9<1641::AID-ANIE1641>3.0.CO;2-L |
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Lithium Amides: Intra-Aggregate Complexation of Lithium and Entropy Control of Basicity Gerbert L. J. van Vliet, Henri Luitjes, Marius Schakel, Gerhard W. Klumpp Published Online: 2 May 2000 DOI10.1002/(SICI)1521-3773(20000502)39:9<1643::AID-ANIE1643>3.0.CO;2-9 |
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Synthesis, Crystal Structure, and Magnetic Behavior of Linear MUIV Complexes (M=Co, Ni, Cu, Zn) Thierry Le Borgne, Eric Rivière, Jérôme Marrot, Jean-Jacques Girerd, Michel Ephritikhine Published Online: 2 May 2000 DOI10.1002/(SICI)1521-3773(20000502)39:9<1647::AID-ANIE1647>3.0.CO;2-M |
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A Catalytic Asymmetric Strecker-Type Reaction: Interesting Reactivity Difference between TMSCN and HCN Masahiro Takamura, Yoshitaka Hamashima, Hiroyuki Usuda, Motomu Kanai, Masakatsu Shibasaki Published Online: 2 May 2000 DOI10.1002/(SICI)1521-3773(20000502)39:9<1650::AID-ANIE1650>3.0.CO;2-P |
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Metric Engineering of Crystalline Inclusion Compounds by Structural Mimicry K. Travis Holman, Michael D. Ward Published Online: 2 May 2000 DOI10.1002/(SICI)1521-3773(20000502)39:9<1653::AID-ANIE1653>3.0.CO;2-7 |
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The Eight Stereoisomers of LNA (Locked Nucleic Acid): A Remarkable Family of Strong RNA Binding Molecules
Vivek K. Rajwanshi, Anders E. Håkansson, Mads D. Sørensen, Stefan Pitsch, Sanjay K. Singh, Ravindra Kumar, Poul Nielsen, Jesper Wengel Published Online: 2 May 2000 DOI10.1002/(SICI)1521-3773(20000502)39:9<1656::AID-ANIE1656>3.0.CO;2-Q |
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Metal Incorporation into and Dimerization of M3E4 Clusters (M=Mo, W; E=S, Se) in Supramolecular Assemblies with Cucurbituril: A Molecular Model of Intercalation Maxim N. Sokolov, Alexander V. Virovets, Danil N. Dybtsev, Olga A. Gerasko, Vladimir P. Fedin, Rita Hernandez-Molina, William Clegg, A. Geoffrey Sykes Published Online: 2 May 2000 DOI10.1002/(SICI)1521-3773(20000502)39:9<1659::AID-ANIE1659>3.0.CO;2-8 |
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Nanoscale Super Clusters of Clusters Assembled around a Dendritic Core Neil Feeder, Junfeng Geng, Peter G. Goh, Brian F. G. Johnson, Caroline M. Martin, Douglas S. Shephard, Wuzong Zhou Published Online: 2 May 2000 DOI10.1002/(SICI)1521-3773(20000502)39:9<1661::AID-ANIE1661>3.0.CO;2-H |
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The Synthesis of Streptogramin Antibiotics: (-)-Griseoviridin and Its C-8 Epimer Curt A. Dvorak, William D. Schmitz, Daniel J. Poon, David C. Pryde, Jon P. Lawson, Richard A. Amos, Albert I. Meyers Published Online: 2 May 2000 DOI10.1002/(SICI)1521-3773(20000502)39:9<1664::AID-ANIE1664>3.0.CO;2-# |
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A Structural Model for the Galactose Oxidase Active Site which Shows Counteranion-Dependent Phenoxyl Radical Formation by Disproportionation Yuichi Shimazaki, Stefan Huth, Akira Odani, Osamu Yamauchi Published Online: 2 May 2000 DOI10.1002/(SICI)1521-3773(20000502)39:9<1666::AID-ANIE1666>3.0.CO;2-O |
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Reaction of Organic Selenocyanates with Hydroxides: The One-Pot Synthesis of Dialkyl Diselenides from Alkyl Bromides Alain Krief, Willy Dumont, Cathy Delmotte Published Online: 2 May 2000 DOI10.1002/(SICI)1521-3773(20000502)39:9<1669::AID-ANIE1669>3.0.CO;2-6 |
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Eliminative Ring Opening of Oxiranium Ions in the Gas Phase Gabriele Renzi, Graziella Roselli, Felice Grandinetti, Antonello Filippi, Maurizio Speranza Published Online: 2 May 2000 DOI10.1002/(SICI)1521-3773(20000502)39:9<1673::AID-ANIE1673>3.0.CO;2-3 |
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High Oxidation State Organocobalt Complexes: Synthesis and Characterization of Dihydridodisilyl Cobalt(V) Species Maurice Brookhart, Brian E. Grant, Christian P. Lenges, Marc H. Prosenc, Peter S. White Published Online: 2 May 2000 DOI10.1002/(SICI)1521-3773(20000502)39:9<1676::AID-ANIE1676>3.0.CO;2-M |
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Traceless, Solid-Phase Synthesis of Biarylmethane Structures through Pd-Catalyzed Release of Supported Benzylsulfonium Salts
Cécile Vanier, Franz Lorg? Alain Wagner, Charles Mioskowski Published Online: 2 May 2000 DOI10.1002/(SICI)1521-3773(20000502)39:9<1679::AID-ANIE1679>3.0.CO;2-4 |
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A Highly Soluble Luminescent Decanuclear Gold(I) Complex with a Propeller-Shaped Structure Vivian Wing-Wah Yam, Eddie Chung-Chin Cheng, Zhong-Yuan Zhou Published Online: 2 May 2000 DOI10.1002/(SICI)1521-3773(20000502)39:9<1683::AID-ANIE1683>3.0.CO;2-1 |
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Metal-Mediated Transfer of Electrons between Two Different C-C Single Bonds That Function as Electron-Donor and Electron-Acceptor Units Federico Franceschi, Euro Solari, Rosario Scopelliti, Carlo Floriani Published Online: 2 May 2000 DOI10.1002/(SICI)1521-3773(20000502)39:9<1685::AID-ANIE1685>3.0.CO;2-Q |
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An Octanuclear FeIII Compound Featuring a New Type of Double Butterfly Iron-Oxo Core Paul Ammala, John D. Cashion, Christopher M. Kepert, Boujemaa Moubaraki, Keith S. Murray, Leone Spiccia, Bruce O. West Published Online: 2 May 2000 DOI10.1002/(SICI)1521-3773(20000502)39:9<1688::AID-ANIE1688>3.0.CO;2-8 |
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FBeNg+ (Ng=He, Ne, Ar): Suitable Cations for Salts of the Lightest Noble Gases? Massimiliano Aschi, Felice Grandinetti Published Online: 2 May 2000 DOI10.1002/(SICI)1521-3773(20000502)39:9<1690::AID-ANIE1690>3.0.CO;2-H |
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Self-Assembly of Rotaxane-Like Complexes with Macrocycles Containing Reversible Coordinate Bonds Kyu-Sung Jeong, Jeung Soon Choi, Sung-Youn Chang, Hong-Young Chang Published Online: 2 May 2000 DOI10.1002/(SICI)1521-3773(20000502)39:9<1692::AID-ANIE1692>3.0.CO;2-5 |
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Silole-Thiophene Alternating Copolymers with Narrow Band Gaps Shigehiro Yamaguchi, Tomoyuki Goto, Kohei Tamao Published Online: 2 May 2000 DOI10.1002/(SICI)1521-3773(20000502)39:9<1695::AID-ANIE1695>3.0.CO;2-O |